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AFCAT · Chemistry · CA01

CA01 — Basic Concepts of Matter

✈ AFCAT General Awareness20 Questions · No Negative Marking
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Question 1 of 20
Which of the following is a physical change?
Melting of ice is a physical change — only the state changes (solid → liquid), no new substance is formed. The chemical composition (H₂O) remains the same and the change is reversible. Burning, rusting, and fermentation are chemical changes — new substances are formed.
Question 2 of 20
The SI unit of amount of substance is:
The mole (mol) is the SI unit for amount of substance. 1 mole = 6.022 × 10²³ particles (Avogadro's number). The SI base units for mass and volume are kilogram (kg) and cubic metre (m³) respectively.
Question 3 of 20
A mixture of iron filings and sulphur can be separated by:
Iron is magnetic; sulphur is not. A magnet easily attracts and separates iron filings from sulphur. This works because the mixture is a physical mixture — no chemical bonds have formed between iron and sulphur. If heated, they form iron sulphide (FeS) which cannot be separated this way.
Question 4 of 20
Avogadro's number (6.022 × 10²³) represents the number of:
Avogadro's number (Nₐ = 6.022 × 10²³ mol⁻¹) is the number of constituent particles (atoms, molecules, or ions) in exactly 1 mole of any substance. Example: 1 mole of water contains 6.022 × 10²³ H₂O molecules.
Question 5 of 20
Which law states that matter can neither be created nor destroyed in a chemical reaction?
Law of Conservation of Mass (Lavoisier, 1789): in any chemical reaction, the total mass of reactants equals the total mass of products. Matter is neither created nor destroyed — only rearranged. This is why chemical equations must be balanced.
Question 6 of 20
The law of definite proportions (constant composition) states that:
Law of Definite Proportions (Proust, 1799): a pure compound always contains the same elements in the same fixed mass ratio, regardless of its source or method of preparation. Example: water always contains H:O by mass = 1:8, whether from a river or a laboratory.
Question 7 of 20
Which among the following is NOT a characteristic of a pure substance?
Pure substances have a FIXED (not variable) boiling point. Variable boiling point is a characteristic of mixtures. A pure substance (element or compound) has: definite composition, fixed melting/boiling points, and cannot be separated by physical means.
Question 8 of 20
Dalton's Law of Multiple Proportions states that:
Law of Multiple Proportions (Dalton): when two elements form more than one compound (e.g., CO and CO₂), the masses of one element (O) combining with a fixed mass of the other (C) are in a simple whole-number ratio. For CO vs CO₂: oxygen ratio = 1:2. This supported the atomic theory.
Question 9 of 20
Which of the following is an example of a heterogeneous mixture?
Soil is a heterogeneous mixture — its composition is not uniform throughout; you can see different components (sand, clay, pebbles, organic matter). Salt solution, sugar solution, and air are homogeneous mixtures (solutions/alloys) — uniform composition throughout.
Question 10 of 20
The molar mass of water (H₂O) is:
Molar mass of H₂O = (2 × 1) + (1 × 16) = 2 + 16 = 18 g/mol. H has atomic mass 1 g/mol; O has atomic mass 16 g/mol. This means 18 grams of water = 1 mole = 6.022 × 10²³ water molecules.
Question 11 of 20
At STP (Standard Temperature and Pressure), 1 mole of any ideal gas occupies:
At STP (0°C, 1 atm), 1 mole of any ideal gas occupies 22.4 litres (molar volume of a gas). This was derived from Avogadro's law. AFCAT note: at SATP (25°C, 1 bar — new standard), molar volume = 24.8 L, but 22.4 L at STP is still the most commonly tested value.
Question 12 of 20
Which of the following best describes an element?
An element is a pure substance consisting of only one type of atom. It cannot be broken down into simpler substances by chemical reactions. Examples: iron (Fe), oxygen (O₂), gold (Au). A compound is made of two or more elements chemically combined.
Question 13 of 20
The empirical formula of a compound gives:
The empirical formula shows the simplest whole-number ratio of atoms. Example: glucose (C₆H₁₂O₆) has empirical formula CH₂O. The molecular formula (C₆H₁₂O₆) shows the actual atoms per molecule. Molecular formula = n × empirical formula (n = whole number).
Question 14 of 20
A 10% (w/v) solution of NaCl means:
% (w/v) = grams of solute per 100 mL of solution. So 10% w/v NaCl = 10 g NaCl dissolved in enough water to make 100 mL total solution. This is commonly used in medical/hospital settings (e.g., normal saline = 0.9% NaCl).
Question 15 of 20
Which of the following is a compound?
Carbon dioxide (CO₂) is a compound — it consists of two different elements (C and O) chemically bonded together in a fixed ratio. Air is a mixture; Brass is an alloy (mixture); Oxygen (O₂) is an element (diatomic).
Question 16 of 20
The percentage composition of an element in a compound is calculated as:
% composition = (mass of element in 1 mole of compound / molar mass of compound) × 100. Example: % of O in H₂O = (16/18) × 100 = 88.9%. This is a fundamental stoichiometry concept tested regularly.
Question 17 of 20
Molarity is defined as:
Molarity (M) = moles of solute / litres of solution. Units: mol/L or M. Example: 1 M NaOH = 1 mole NaOH dissolved in enough water to make 1 litre of solution. Molality = moles per kg of solvent (different — not affected by temperature).
Question 18 of 20
Which of the following statements about compounds is CORRECT?
Compounds: fixed composition (definite ratio of elements), properties DIFFER from constituent elements (e.g., water is liquid while H₂ and O₂ are gases at room temperature), can ONLY be separated by chemical methods (not physical). These distinguish compounds from mixtures.
Question 19 of 20
The gram formula mass of CaCO₃ (calcium carbonate) is:
Molar mass of CaCO₃ = Ca + C + 3O = 40 + 12 + (3×16) = 40 + 12 + 48 = 100 g/mol. CaCO₃ is limestone/marble. This is a commonly tested compound — remember Ca=40, C=12, O=16.
Question 20 of 20
Which of the following correctly states Avogadro's Law?
Avogadro's Law (1811): equal volumes of all gases, measured at the same temperature and pressure, contain equal numbers of molecules. This explains why the molar volume of any ideal gas at STP = 22.4 L. Option D is Boyle's Law.